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991.
992.
综述了单螺杆挤出机内聚合物熔体层流混合机理的研究进展,对提高混合的措施进行了分析总结,指出了进一步强化混合效果的方法。 相似文献
993.
The density profile of electrosynthesized polymeric layers on carbon fibers is obtained from gravimetric and scanning electron microscopy (SEM) data. The coating density ρ is found to decrease with increasing radial distance, r, subject to the power law . Based on a modified diffusion-limited aggregation (DLA) model, it is shown that lattice Monte Carlo simulation of the coating process predicts the experimentally observed power law exponent. 相似文献
994.
将内层胶配方中合成橡胶用量由原来的30份提高到40份,通过改变炭黑的品种、添加5份白炭黑等方法降低原生产配方的含胶率。试验结果表明,通过配方调整,试验胶料的工艺性能、物理性能和实际使用性能与原配方生产的内层胶接近。 相似文献
995.
采用毛细管动态流变仪,选用PELD、PP、PS和PA等典型物料,研究了毛细管动态挤出下各聚合物熔体的非线性流变行为。结果表明,不同物料的流变行为对振动力场的响应特性有较大差异,只有在一定的振幅和频率下振动力场才能有效降低熔体的黏度。实验首次发现,PP、PS和PA存在窄的振动参数区域,在此区域内,熔体的动态表观黏度值大于相应的稳态值,出现“加振变黏”现象。这一新的发现表明,并非“只要引入振动就一定有利于聚合物材料的成型加工”,必须考虑不同分子结构的聚合物材料对振动的不同响应规律。 相似文献
996.
Nor?Azowa?IbrahimEmail author Faraj?Abu-Ilaiwi Mohamad?Zaki?Ab.?Rahman Mansor?B.?Ahmad Khairul?Zaman?M.?Dahlan Wan?Md?Zin?Wan?Yunus 《Journal of Polymer Research》2005,12(3):173-179
Grafting of acrylamide (AAm) onto oil palm empty fruits bunch fiber using hydrogen peroxide as initiator and methyl acrylate as comonomer was investigated. The amount of comonomer needed to make grafting of acrylamide possible was determined. The percentage of poly(acrylamide) and the comonomer in the final graft copolymer was estimated by elemental analysis. Results obtained indicated that methyl acrylate facilitated the incorporation of acrylamide monomer onto OPEFB. The reactivity ratios for both monomers were determined by using Fineman–Ross plot. The effects of reaction temperature and period as well as amount of the initiator, solvent, monomer and comonomer on the percentage of grafting at fixed amount of comonomer (11 mmol) were studied. Maximum percentage of grafting was achieved when the amount of initiator and solvent 3.98×10−3 mol and 50 mL respectively. The optimum reaction temperature was 50 ○C and the reaction period was 90 min. Highest percentage of grafting was 232% when 25.6 mmol of acrylamide was used under these optimum conditions. The presence of functional group in the grafted polymer is characterized by infrared spectroscopy and the surface morphology is observed by scanning electron microscopy. Thermoanalytic investigation on OPEFB and OPEFB-g-PAAM were carried out to evaluate the thermal stability and respective activation energy of the materials. 相似文献
997.
998.
Infra-red measurements of the dichroic ratio of atactic polystyrene and poly(2,6-dimethyl 1,4-phenylene oxide) absorption bands provide a valuable method for the determination of orientation as well as relaxation of chains of both polymers during stretching of their compatible blends. Influence of strain rate, temperature of stretching, and molecular weight of the polymers on orientation of both polymer chains in blends containing up to 35% PPO has been studied. Orientation relaxation for both polymers has been analysed using Lodge's constitutive equation. Master curves have been obtained for PPO and PS in the blends at a reference temperature T0 = Tg + 10°C. Results are interpreted in terms of an hindrance of relaxation of PS chains induced by interaction with a highly-oriented PPO network which slowly relaxes. 相似文献
999.
1000.